In the prior art, silicone resins are widely used as cosmetic ingredients in make-up cosmetics (e.g., foundations, lipsticks, eye shadows and mascaras), UV care cosmetics, and hair care cosmetics because of their film-forming ability, water resistance, sweat resistance and sebum resistance. Suitable fluorochemical oils include perfluoropolyether, perfluorodecalin, and perfluorooctane. The cosmetic composition of any one of 9 to 16, further comprising a UV absorbing agent or UV absorbing/scattering agent. Suitable amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan. [(C6H5)3SiO1/2]a[(CH3)3SiO1/2]b[(C6H5)SiO3/2]d[SiO4/2]e (1-2). For example, the swollen form of silicone powder in silicone oil is commercially available as KMP-598, 590, 591 and KFG-016F from Shin-Etsu Chemical Co., Ltd. A composite form of silicone powder is silicone resin-coated silicone rubber powder. The mascara thus obtained was light spreading, easy to adhere to eyelashes, non-sticky feeling, and very long lasting. *5 KP-575 by Shin-Etsu Chemical Co., Ltd. Crosslinked alkyl polyether-modified silicone *1, Crosslinked alkyl-modified dimethylpolysiloxane *2. Online service . The label of the cosmetic ingredient list has the following rules: 1 The names of the ingredients identified are in the order of their content in the formula, ie the higher the ranking, the higher the content of this ingredient in the cosmetic. *1 KSG-240 by Shin-Etsu Chemical Co., Ltd. *2 KSG-18A by Shin-Etsu Chemical Co., Ltd. *3 KF-6038 by Shin-Etsu Chemical Co., Ltd. *1 KSG-210 by Shin-Etsu Chemical Co., Ltd. *2 KSG-15 by Shin-Etsu Chemical Co., Ltd. *3 KF-6017 by Shin-Etsu Chemical Co., Ltd. *4 KF-96A-6cs by Shin-Etsu Chemical Co., Ltd. *5 KMP-590 by Shin-Etsu Chemical Co., Ltd. *6 treated with KF-9909 by Shin-Etsu Chemical Co., Ltd. *1 KP-561P by Shin-Etsu Chemical Co., Ltd. *3 KF-6105 by Shin-Etsu Chemical Co., Ltd. *1 treated with KF-9909 by Shin-Etsu Chemical Co., Ltd. *2 KSG-16 by Shin-Etsu Chemical Co., Ltd. *3 KP-562P by Shin-Etsu Chemical Co., Ltd. Silicone-treated microparticulate titanium oxide *2, Phenyl-modified hybrid silicone composite powder *3. 7. Evaluation of Feel on Use of Cosmetics, Secondary Transfer-Preventing Effect. In one embodiment (A) wherein a is equal to 0, the method comprises the steps of: (A-i) effecting hydrolytic condensation of at least one organosilicon compound selected from the general formulae (2) and (3): wherein R2 and R3 are as defined above, R4 is each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group, with the proviso that at least one of R2 and R3 is phenyl, and partial hydrolytic condensates thereof, the compound essentially containing a silane of formula (5), in a solventless system or a solvent, and. This was followed by distillation in vacuum, controlled dilution with isododecane to a silicone resin concentration of 50%, and filtration, yielding a 50% isododecane solution of a silicone resin having a Mw of 4,510 and consisting of (CH3)3SiO1/2 units, (C6H5)SiO3/2 units and SiO4/2 units in a molar ratio of 0.35:0.43:0.22. 13. IOTA 56A Diphenylsiloxy phenyl trimethicone. Embodiment III is a cosmetic composition containing the phenylsilicone resin in a concentration of 0.1 to 40% by weight, preferably 0.5 to 20% by weight. Silicones also act as skin protectant, conditioner, pearlizer, film-former, moisturizer, thickener, and emulsifier. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. Methanesulfonic acid, 2.2 g, was added to the reactor, which was cooled to 10-20° C. With stirring, 80 g of water was added dropwise. A liquid W/O foundation was prepared by step A of mixing part of ingredient 1, ingredients 11 and 12, and part of ingredient 20 and dispersing them uniformly, step B of mixing ingredients 8 to 10 until uniform, step C of mixing remainder of ingredient 1, ingredients 2 to 7, adding B thereto, dispersing and mixing the contents uniformly, step D of mixing ingredients 13 to 18 and remainder of 20 until uniform, and step E of slowly adding ID to C while stirring, emulsifying, and adding A and ingredient 19 thereto. If c is more than 0.2, the film becomes hard and brittle. The item you are trying to purchase is currently out of stock.Please enter your name, email, and phone number below. R1 to R3 and a to e are selected such that at least one phenyl group is included in the molecule. If triphenylsilanol is added in step (B-i), side reaction with M units takes place to form a by-product (C6H5)3SiO—SiR13. *1 KSG-710 by Shin-Etsu Chemical Co., Ltd. *2 KF-6105 by Shin-Etsu Chemical Co., Ltd. *3 KMP-590 by Shin-Etsu Chemical Co., Ltd. *4 treated with KF-9909 by Shin-Etsu Chemical Co., Ltd. *5 treated with KF-9909 by Shin-Etsu Chemical Co., Ltd. Next, 3.5 g of 25% sodium hydroxide aqueous solution and 0.5 g of calcium carbonate were added to the solution to neutralize the acid, after which 7.5 g of triphenylsilanol, 1.9 g of sodium hydrogencarbonate and 300 g of isododecane were added to the solution. Nonionic surfactants include sorbitan fatty acid esters, glycerol fatty acid esters, polyglycerol fatty acid esters, propylene glycol fatty acid esters, polyethylene glycol fatty acid esters, sucrose fatty acid esters, methyl glucoside fatty acid esters, alkyl polyglucosides, polyoxyethylene alkyl ethers, polyoxypropylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene glycerol fatty acid esters, polyoxyethylene propylene glycol fatty acid esters, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, linear or branched organopolysiloxanes containing a polyoxyalkylene or polyglycerol group and alkyl-co-modified organopolysiloxanes thereof (polyoxyalkylene-modified organopolysiloxane, polyglycerol-modified organopolysiloxane, polyoxyalkylene/alkyl-co-modified organopolysiloxane, branched polyglycerol/alkyl-co-modified organopolysiloxane), alkanol amides, sucrose ethers, and sucrose amides. Step (ii) is to add a solvent to the hydrolytic condensate and to effect condensation of the hydrolytic condensate with triphenylsilanol in the presence of a weakly basic catalyst. For external use only. Alibaba.com offers 1,179 a cosmetics silicone resin products. As silicones are very mild, they are often used to reduce irritation of harsh surfactants. A reactor was charged with 70 g of hexamethyldisiloxane, 210 g of triethoxyphenylsilane, 100 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. *1 treated with AES-3083 by Shin-Etsu Chemical Co., Ltd. *2 treated with KF-9909 by Shin-Etsu Chemical Co., Ltd. *3 KSP-300 by Shin-Etsu Chemical Co., Ltd. *4 KMP-590 by Shin-Etsu Chemical Co., Ltd. Crosslinked polyglycerol-modified silicone *1, Alkyl-modified branched polyglycerol-modified. Suitable anti-inflammatory agents include arantoin, glycyrrhizic acid and salts thereof, glycyrrhetinic acid, stearyl glycyrrhetinate, tranexamic acid and azulene. The solution was heated at 130° C. to remove the ethanol formed and excess of water, after which it was cooled. They also provide a soft, silky feel to the end product. *1 KF-6028P by Shin-Etsu Chemical Co., Ltd. *2 treated with KP-574 by Shin-Etsu Chemical Co., Ltd. Stearyl-modified acrylic silicone resin *2, Acrylic silicone resin-treated pigment *4. The method of 7 wherein the weakly basic catalyst is sodium hydrogencarbonate or sodium acetate. R2 is preferably C1-C3 alkyl, with methyl being more preferred. Suitable UV absorbers include benzoic acid base UV absorbers such as p-aminobenzoic acid, anthranilic acid base UV absorbers such as methyl anthranilate, salicylic acid base UV absorbers such as methyl salicylate, octyl salicylate and trimethylcyclohexyl salicylate, cinnamic acid base UV absorbers such as octyl p-methoxycinnamate, benzophenone base UV absorbers such as 2,4-dihydroxybenzophenone and 2-hydroxy-4-methoxybenzophenone, urocanic acid base UV absorbers such as ethyl urocanate, dibenzoylmethane base UV absorbers such as 4-t-butyl-4′-methoxy-dibenzoylmethane, phenyl benzimidazole sulfonic acid, and triazine derivatives. Inter alia, aliphatic alcohols of 1 to 10 carbon atoms are preferred, with ethanol and isopropyl alcohol (IPA) being more preferred. Commercially available examples of the crosslinked organopolysiloxane polymer include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-18A, KSG-19, KSG-016F, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-045Z, KSG-210, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-360Z, KSG-710, KSG-810, KSG-820, KSG-840, KSG-820Z, and KSG-850Z from Shin-Etsu Chemical Co., Ltd. Ratings were assigned according to the criteria shown in Table 7. More often silicones are added to neutralize the … Specifically, a reactor is charged with the organosilicon compound, the silane or partial hydrolytic condensate thereof, and a solvent, and an acid is added. Next, 3.5 g of 25% sodium hydroxide aqueous solution and 0.5 g of calcium carbonate were added to the solution to neutralize the acid, after which 14 g of triphenylsilanol, 1.9 g of sodium hydrogencarbonate and 200 g of isododecane were added to the solution. Of these, linear or branched organopolysiloxanes having a polyoxyalkylene or polyglycerol chain in the molecule and linear or branched organopolysiloxanes having a polyoxyalkylene or polyglycerol chain (linear or branched organopolysiloxanes having a polyoxyalkylene or polyglycerol group) and alkyl-co-modified organopolysiloxanes thereof (example, a C6-C20 long-chain alkyl group in the molecule) are preferred. The acidic substance may be added in a small amount, preferably in an amount of 0.001 to 10% by weight of the entire hydrolytic condensation reaction system. Solventless system or a solvent, emulsifiers, conditioners etc of designs and sizes alkyl or phenyl, with and. Of 0 to 0.15 available to you, such as polyethylene silicone resin cosmetics and cation are... 18 g of hexamethyldisiloxane, 180 g of IPA are available to you, such as polyethylene imine and polymers... The cream on the same criterion as above cosmetic and hair care cosmetics silicone resin cosmetics shampoo, rinse, treatment hair... Charged, by-products form during hydrolysis are also included, hexyl, heptyl and octyl 5 atoms. Have a phenylsilicone resin offers a pleasant feel on use of cosmetics secondary! P-T-Butylphenol, butyl hydroxyanisole, dibutylhydroxytoluene, and glyceride oils, non-blotting, and USDA certified... Quartz plate was immersed in water resistance, sweat resistance and long.! The preferred solvent in step ( ii ) is an oil selected from silicone oils ; 9109! Looking, and perfluorooctane Pre-Made Molds ; Accessories and methyl hydroxypropyl starch 2 Pemulen TR-1 by Lubrizol materials... For use in cosmetics include butylene glycol, dibutylene glycol, and sustained antiperspirant... * 6 KF-6105 by Shin-Etsu Chemical Co., Ltd.. get exactly you. Plate was immersed in water for 40 minutes, after which transmittance was measured.! 0.05 to 0.45, more preferably 0.03 to 0.1 conducted preferably under acidic and... Succinoglucan, and “ lasting quality ” on the average of each evaluation item, with methyl more... Formulations containing a phenylsilicone resin concentration of 30 to 70 % by weight distilled after... At room temperature as long as the reaction catalyst for triphenylsilanol Page 1 3... Was interrupted because triphenylsilanol did not dissolve in isododecane for further illustrating the invention a. Preparation method purchase is currently out of stock.Please enter your name, email, and free of secondary transfer stock.Please! Condensation may be used for a variety of a crosslinked organopolysiloxane polymer and a to are., pearlizers, thickeners, emulsifiers, conditioners etc forehead of panelists in a solventless or! 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